Draw the following species (use VSEPR to draw the correct shape) and indicate the hybridization of the central atom in the following: (a) \( \mathrm{AsCl}_{3} \) (b) \( \mathrm{CH}_{2} \mathrm{O} \) (c) \( \mathrm{PCl}_{2} \mathrm{~F}_{3} \) (d) \( \mathrm{CCl}_{2} \mathrm{~F}_{2} \) (e) \( \mathrm{ICl}_{2}^{-} \) (f) \( \mathrm{IF}_{6}^{+} \)

14 Nitrogen has atomic number 7 and oxygen has atomic number 8 What is total number of electrons in \( \left(\mathrm{NO}_{3}\right)^{-} \)ion ? \( \begin{array}{ll}\text { (a) } 15 \mathrm{e}^{-} & \text {(b) } 31 \mathrm{e}^{-} \\ \text {(c) } 32 \mathrm{e}^{-} & \text {(d) } 46 \mathrm{e}^{-}\end{array} \)

5. At what pressure will 7.89 g of ammonia gas, \( \mathrm{NH}_{3} \), occupy 7.46 L at \( 20.0^{\circ} \mathrm{C} \) ?

Questão 1) São dadas as seguintes equações termoquímicas: \( \begin{array}{l}\text { I) } \mathrm{C}_{(\mathrm{s})}+\mathrm{O}_{2(\mathrm{~g})} \longrightarrow \mathrm{CO}_{2(\mathrm{~g})} \quad \Delta \mathrm{H}=-94,1 \mathrm{kcal} / \mathrm{mol} \\ \begin{array}{l}\text { II) } \mathrm{H}_{2(\mathrm{~g})}+1 / 2 \mathrm{O}_{2(\mathrm{~g})}\end{array} \longrightarrow \mathrm{H}_{2} \mathrm{O}_{(\mathrm{l})} \quad \Delta \mathrm{H}=-68,3 \mathrm{kcal} / \mathrm{mol} \\ \text { III) } \mathrm{C}_{(\mathrm{s})}+2 \mathrm{H}_{2(\mathrm{~g})} \longrightarrow \mathrm{CH}_{4(\mathrm{~g})} \quad \Delta \mathrm{H}=-17,9 \mathrm{kcal} / \mathrm{mol} \\ \text { Calcule o calor liberado, em kcal, na reação de combustão de } 1 \text { mol de gás metano. } \\ \mathrm{CH}_{4(\mathrm{~g})}+2 \mathrm{O}_{2(\mathrm{~g})} \longrightarrow \mathrm{CO}_{2(\mathrm{~g})}+2 \mathrm{H}_{2} \mathrm{O}_{(\mathrm{l})} \quad \Delta \mathrm{H}=\text { ? }\end{array} \$ \begin{array}{l}\longrightarrow\end{array} \)

Questão 2) Qual o valor da variação de entalpia da reação a seguir? \[ C_{(g r \text { fite })}+\mathrm{O}_{2(g)} \rightarrow \mathrm{CO}_{2(g)} \] Dados: \( \mathrm{C}_{(\mathrm{grffte})}+\frac{1}{2} \mathrm{O}_{2(g)} \rightarrow \mathrm{CO}_{(\mathfrak{g})} \quad \Delta H_{1}=-110,3 \mathrm{KJ} \) \( \mathrm{CO}_{(g)}+\frac{1}{2} \mathrm{O}_{2(g)} \rightarrow \mathrm{CO}_{2(g)} \quad \Delta H_{2}=-283,0 \mathrm{KJ} \)

5) \( \mathrm{Ag}_{2} \mathrm{O} \rightarrow \)