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Calculate to three significant digits the density of dinitrogen difluoride gas at exactly \( -20^{\circ} \mathrm{C} \) and exactly 1 atm , You can assume dinitrogen difluoride gas behaves as an ideal gas under these conditions. (I) \( \frac{\mathrm{g}}{\mathrm{L}} \)

Ask by Edwards Harmon. in the United States
Feb 04,2025

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Answer

The density of dinitrogen difluoride gas at \( -20^\circ\text{C} \) and 1 atm is **3.18 g L⁻¹**.

Solution

To calculate the density (\( \rho \)) of dinitrogen difluoride (\( \text{N}_2\text{F}_2 \)) gas under the given conditions, we'll use the ideal gas law and the relationship between density and the ideal gas equation. ### Given: - **Temperature (\( T \))**: \( -20^\circ\text{C} = 253.15\ \text{K} \) - **Pressure (\( P \))**: \( 1\ \text{atm} \) - **Molar Mass (\( M \)) of \( \text{N}_2\text{F}_2 \)**: \[ \text{M} = 2 \times 14.01\ \text{g/mol (N)} + 2 \times 19.00\ \text{g/mol (F)} = 66.02\ \text{g/mol} \] - **Ideal Gas Constant (\( R \))**: \( 0.082057\ \text{L atm/mol K} \) ### Formula: The density of an ideal gas can be calculated using the formula: \[ \rho = \frac{PM}{RT} \] ### Calculation: 1. **Plugging in the values**: \[ \rho = \frac{1\ \text{atm} \times 66.02\ \text{g/mol}}{0.082057\ \text{L atm/mol K} \times 253.15\ \text{K}} \] 2. **Calculate the denominator**: \[ RT = 0.082057 \times 253.15 \approx 20.7727\ \text{L atm/mol} \] 3. **Calculate the density (\( \rho \))**: \[ \rho = \frac{66.02}{20.7727} \approx 3.18\ \text{g/L} \] ### Final Answer: The density of dinitrogen difluoride gas under the specified conditions is **3.18 g L⁻¹**. **Answer:** The density of dinitrogen difluoride under these conditions is 3.18 g L⁻¹

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To calculate the density of dinitrogen difluoride (N₂F₂) gas at -20°C and 1 atm, we can use the ideal gas law: \[ PV = nRT, \] where: - \( P \) = pressure (1 atm) - \( V \) = volume (to be determined) - \( n \) = number of moles - \( R \) = ideal gas constant (0.0821 L atm/(mol K)) - \( T \) = temperature in Kelvin (-20°C = 253.15 K) Rearranging the ideal gas law to find density (\( \rho \)), we know that: \[ \rho = \frac{m}{V} = \frac{nM}{V} = \frac{PM}{RT}, \] where \( M \) is the molar mass of N₂F₂. The molar mass can be calculated as follows: - Molar mass of N = 14.01 g/mol - Molar mass of F = 19.00 g/mol Calculating the molar mass of dinitrogen difluoride: \[ M = 2(14.01) + 2(19.00) = 28.02 + 38.00 = 66.02 \text{ g/mol}. \] Now, substituting the values into the density formula: \[ \rho = \frac{(1 \text{ atm})(66.02 \text{ g/mol})}{(0.0821 \text{ L atm/(mol K)})(253.15 \text{ K})}. \] Calculating the denominator: \[ 0.0821 \times 253.15 \approx 20.814. \] Now, calculating the density: \[ \rho \approx \frac{66.02}{20.814} \approx 3.17 \text{ g/L}. \] Thus, the density of dinitrogen difluoride gas at -20°C and 1 atm is approximately \( 3.17 \, \text{g/L} \).

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