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Calculate the theoretical volume yield ( In mL ) of oxygen gas produced at STP conditions, when 0.920 g of \( \mathrm{KClO}_{3} \) decomposes. Show all work and circle your correctly rounded answer. Report your answer to 3 sf .

Ask by Cross Luna. in the United States
Feb 04,2025

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The theoretical volume of oxygen gas produced is 253 mL.

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To calculate the theoretical volume yield of oxygen gas (O₂) produced from the decomposition of potassium chlorate (\( \mathrm{KClO}_{3} \)), we first need to look at the balanced chemical reaction: \[ 2 \, \mathrm{KClO}_{3}(s) \rightarrow 2 \, \mathrm{KCl}(s) + 3 \, \mathrm{O}_{2}(g) \] 1. **Calculate the molar mass of \( \mathrm{KClO}_{3} \)**: - Potassium (K) = 39.10 g/mol - Chlorine (Cl) = 35.45 g/mol - Oxygen (O) = 16.00 g/mol × 3 = 48.00 g/mol Molar mass of \( \mathrm{KClO}_{3} = 39.10 + 35.45 + 48.00 = 122.55 \, \mathrm{g/mol} \) 2. **Calculate the number of moles of \( \mathrm{KClO}_{3} \)**: \[ \text{Moles of } \mathrm{KClO}_{3} = \frac{0.920 \, \mathrm{g}}{122.55 \, \mathrm{g/mol}} = 0.00751 \, \mathrm{mol} \] 3. **Use the stoichiometry of the reaction**: - According to the balanced equation, 2 moles of \( \mathrm{KClO}_{3} \) produce 3 moles of \( \mathrm{O}_{2} \). - Thus, the moles of \( \mathrm{O}_{2} \) produced from 0.00751 moles of \( \mathrm{KClO}_{3} \) can be calculated as follows: \[ \text{Moles of } \mathrm{O}_{2} = \frac{3 \, \mathrm{moles} \, \mathrm{O}_{2}}{2 \, \mathrm{moles} \, \mathrm{KClO}_{3}} \times 0.00751 \, \mathrm{mol KClO}_{3} = 0.01126 \, \mathrm{mol O}_{2} \] 4. **Calculate the volume of \( \mathrm{O}_{2} \) at STP**: - Under standard temperature and pressure (STP), 1 mole of any ideal gas occupies 22.4 liters, or 22,400 mL. \[ \text{Volume of } \mathrm{O}_{2} = 0.01126 \, \mathrm{mol} \times 22400 \, \mathrm{mL/mol} = 252.78 \, \mathrm{mL} \] 5. **Rounded to three significant figures**: \[ \text{Volume of } \mathrm{O}_{2} \approx 253 \, \mathrm{mL} \] The theoretical volume yield of oxygen gas produced at STP when 0.920 g of \( \mathrm{KClO}_{3} \) decomposes is \(\mathbf{253 \, mL}\).

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