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DISCUSSION OF RESULTS Which property of sulphuric acid makes it suitable to use as a catalyst for the preparation of esters? Why do we heat the test tube in a water bath and not directly over a flame? With reference to the characteristic smells of esters, name TWO examples where esters are used in different industries. 3.

Ask by Powell Bolton. in South Africa
Feb 27,2025

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1. Sulphuric acid works well as a catalyst for making esters because it is a strong acid that helps in the reaction by protonating the carbonyl group of the carboxylic acid, making it more reactive. It also removes water, which drives the reaction towards ester formation. 2. We use a water bath to heat the test tube instead of a direct flame because a water bath provides gentle and even heating. Direct flame can cause uneven heating, which might damage the reactants or products and is less safe. 3. Esters have a sweet and fruity smell. They are used in: - **Food and Beverage Industry**: Isoamyl acetate (banana scent) is used as a flavoring agent. - **Pharmaceutical and Cosmetics Industry**: Methyl salicylate (wintergreen scent) is used in topical analgesics and fragrances.

Solution

1. Sulphuric acid is ideal as a catalyst in esterification because it is a very strong acid and a potent dehydrating agent. As a strong acid, it protonates the carbonyl oxygen of the carboxylic acid, making the carbonyl carbon more electrophilic and thus more susceptible to attack by the alcohol. Its dehydrating property also helps remove water (one of the products), driving the equilibrium toward ester formation. 2. Heating in a water bath is preferred over direct heating with a flame because the water bath provides gentle, even, and controlled heating. Direct flame can cause localized overheating, leading to breakdown of reactants or products (and even risk bumping or scorching), whereas a water bath minimizes these risks by maintaining a consistent temperature. 3. Esters are well known for their pleasant and characteristic fruity aromas, which make them valuable in different industries. For example:  • Isoamyl acetate, which smells like bananas, is widely used in the food and beverage industry as a flavoring agent.  • Methyl salicylate, known for its wintergreen scent, is used in the pharmaceutical and cosmetic industries in products such as topical analgesics and fragrances.

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Sulphuric acid is a strong acid and an excellent dehydrating agent, which makes it highly suitable as a catalyst in the preparation of esters. It helps to speed up the esterification reaction between alcohols and carboxylic acids by protonating the reactants, thus facilitating the release of water and driving the reaction towards the formation of esters. Heating in a water bath rather than directly over a flame helps maintain a controlled temperature, preventing overheating and potential splattering of the reaction mixture. This method ensures even heating and reduces the risk of ignition of any volatile substances present, contributing to a safer laboratory environment. Esters not only provide delightful fragrances but are also multi-talented! For instance, isoamyl acetate, known for its banana scent, is often used in the food industry as a flavoring agent, while ethyl acetate, with its sweet smell, finds applications as a solvent in the nail polish and paint industries. So, the next time you enjoy a fruity treat or use nail polish remover, you can thank esters!

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