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15.17 Calculate the pH of a 1.5 M solution of each of the following compounds (see Appendix E for \( K \) values): (a) \( \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{~N} \); (b) \( \mathrm{HONH}_{2} \); and (c) \( \mathrm{HCO}_{2} \mathrm{H} \).

Ask by Weber Ramos. in Canada
Mar 09,2025

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Answer

Cannot calculate the pH for any of the compounds because the \( K \) values are not provided.

Solution

To calculate the pH of a solution, we can use the formula: \[ \text{pH} = -\log_{10}[\text{H}^+] \] where \([\text{H}^+]\) is the concentration of hydrogen ions in the solution. Given that the solution is 1.5 M, we can calculate the pH for each compound by finding the concentration of hydrogen ions \([\text{H}^+]\) using the \(K\) values provided in Appendix E. Let's calculate the pH for each compound: (a) \( \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{~N} \) The \(K\) value for \( \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{~N} \) is not provided in the given information. Therefore, we cannot calculate the pH for this compound. (b) \( \mathrm{HONH}_{2} \) The \(K\) value for \( \mathrm{HONH}_{2} \) is not provided in the given information. Therefore, we cannot calculate the pH for this compound. (c) \( \mathrm{HCO}_{2} \mathrm{H} \) The \(K\) value for \( \mathrm{HCO}_{2} \mathrm{H} \) is not provided in the given information. Therefore, we cannot calculate the pH for this compound. Since the \(K\) values are not provided, we cannot calculate the pH for any of the compounds.

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The Deep Dive

To calculate the pH of each of these compounds, we first need to identify their nature as acids or bases, along with their dissociation constants (\( K_a \) or \( K_b \)). For \( \mathrm{C}_{5} \mathrm{H}_{5} \mathrm{~N} \) (Pyridine), it is a weak base, and we can use its \( K_b \) value to find the \( K_a \) of its conjugate acid and then calculate the pH. For a 1.5 M solution, the equilibrium calculation gives us a pOH, which we then convert to pH. For \( \mathrm{HONH}_{2} \) (Hydrazine), it is also a weak base, so we apply the same method using its \( K_b \) value. Lastly, \( \mathrm{HCO}_{2} \mathrm{H} \) (Formic acid) is a weak acid. Here, we can directly use its \( K_a \) to find the concentration of \( \mathrm{H}^+ \) ions in solution, allowing us to calculate the pH straightforwardly. Now, let’s get to solving these equations! Make sure to look up the specific \( K \) values for precise calculations. To avoid common mistakes, always ensure that you have the right dissociation constants and remember that pH is calculated from the concentration of \( \mathrm{H}^+ \) ions, while pOH is calculated from the concentration of \( \mathrm{OH}^- \) ions. Misjudging if a compound is an acid or base can lead to significant errors in calculation.

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