Pregunta
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Hydrogen diffuses 4 times as rapidly as a certain
gas. What is the density and molecular weight of the
gas when that of Hydrogen is unity?

Ask by Luna Nichols. in Pakistan
Mar 30,2025

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The density of the gas is and its molecular weight is .

Solución

According to Graham’s law of effusion, the rate of diffusion of a gas is inversely proportional to the square root of its density. If hydrogen diffuses 4 times as rapidly as the gas, we can express this relationship as follows:
where and are the diffusion rates of hydrogen and the gas, respectively, and and are their densities. Given that and , we can find .
Substituting the known values into Graham’s law gives us:
Squaring both sides results in:
Using the relationship between density and molecular weight, we know that:
where and are the molecular weights of the gas and hydrogen, respectively. Given that (for hydrogen), we can express this as:
Thus, .

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The Deep Dive

When hydrogen diffuses 4 times as rapidly as another gas, it is a classic application of Graham’s law of effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its density (or molecular weight). If we let the molecular weight of hydrogen (H₂) be 2 g/mol (since the density is unity), we can denote the molecular weight of the unknown gas as M. According to Graham’s law:
Given that hydrogen diffuses 4 times as rapidly as the gas, we have:
Squaring both sides gives:
So, the molecular weight g/mol. For the density, using the relationship at constant temperature and pressure, the unknown gas would have a density of 16, since hydrogen has a density of 1.

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