Pregunta
Hydrogen diffuses 4 times as rapidly as a certain
gas. What is the density and molecular weight of the
gas when that of Hydrogen is unity?
gas. What is the density and molecular weight of the
gas when that of Hydrogen is unity?
Ask by Luna Nichols. in Pakistan
Mar 30,2025
Solución de inteligencia artificial de Upstudy
Respuesta verificada por el tutor
Responder
The density of the gas is
and its molecular weight is
.
Solución
According to Graham’s law of effusion, the rate of diffusion of a gas is inversely proportional to the square root of its density. If hydrogen diffuses 4 times as rapidly as the gas, we can express this relationship as follows:
where
and
are the diffusion rates of hydrogen and the gas, respectively, and
and
are their densities. Given that
and
, we can find
.
Substituting the known values into Graham’s law gives us:
Substituting the known values into Graham’s law gives us:
Squaring both sides results in:
Using the relationship between density and molecular weight, we know that:
where
and
are the molecular weights of the gas and hydrogen, respectively. Given that
(for hydrogen), we can express this as:
Thus,
.
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The Deep Dive
When hydrogen diffuses 4 times as rapidly as another gas, it is a classic application of Graham’s law of effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its density (or molecular weight). If we let the molecular weight of hydrogen (H₂) be 2 g/mol (since the density is unity), we can denote the molecular weight of the unknown gas as M. According to Graham’s law:
Given that hydrogen diffuses 4 times as rapidly as the gas, we have:
Squaring both sides gives:
So, the molecular weight
g/mol. For the density, using the relationship
at constant temperature and pressure, the unknown gas would have a density of 16, since hydrogen has a density of 1.

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