SP3. The initial temperature of 140 g of ice is \( -22^{\circ} \mathrm{C} \). The specific heat capacity of ice is \( 0.5 \mathrm{cal} / \mathrm{g} \cdot \mathrm{C}^{\circ} \), and water's is \( 1 \mathrm{cal} / \mathrm{g} \cdot \mathrm{C}^{\circ} \). The latent heat of fusion of water is \( 80 \mathrm{cal} / \mathrm{g} \). a. How much heat is required to raise the ice to \( 0^{\circ} \mathrm{C} \) ? b. How much additional heat is required to completely melt the ice after it has reached \( 0^{\circ} \mathrm{C} \) ? c. How much additional heat is required to heat the water (obtained by melting the ice) to \( 27^{\circ} \mathrm{C} \) ? d. What is the total heat that must be added to convert the 140 g of ice at \( -22^{\circ} \mathrm{C} \) to water at \( +27^{\circ} \mathrm{C} \) ? e. Examine your answers to parts a, b, and c . Which takes the most energy: heating ice to the melting point, melt- ing the ice, or heating the cold water to the final temperature? f. Can we find this total heat simply by computing how much heat is required to melt the ice and adding the amount of heat required to raise the temperature of 140 g of water by \( 49^{\circ} \mathrm{C} \) ? Explain.
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The Deep Dive
To calculate the heat required to raise the temperature of the ice to \( 0^{\circ} \mathrm{C} \), we can use the formula \( Q = mc\Delta T \). Here, \( m = 140 \, \text{g} \), \( c = 0.5 \, \text{cal/g} \cdot \mathrm{C}^{\circ} \), and \( \Delta T = 22 \, \text{C}^{\circ} \) (from \(-22 \mathrm{C}^{\circ}\) to \(0 \mathrm{C}^{\circ}\)). So, \[ Q = 140 \times 0.5 \times 22 = 1540 \, \text{cal}. \] For the heat required to melt the ice, we apply the latent heat of fusion: \[ Q_{\text{melt}} = m \times L_f \] \[ Q_{\text{melt}} = 140 \, \text{g} \times 80 \, \text{cal/g} = 11200 \, \text{cal}. \] Next, to heat the resulting water from \( 0^{\circ} \mathrm{C} \) to \( 27^{\circ} \mathrm{C} \), we again use the heat formula: \[ Q_{\text{heat}} = mc\Delta T \] \[ Q_{\text{heat}} = 140 \, \text{g} \times 1 \, \text{cal/g} \cdot \mathrm{C}^{\circ} \times 27 \, \text{C}^{\circ} = 3780 \, \text{cal}. \] Now, the total heat required is: \[ Q_{\text{total}} = Q + Q_{\text{melt}} + Q_{\text{heat}} \] \[ Q_{\text{total}} = 1540 \, \text{cal} + 11200 \, \text{cal} + 3780 \, \text{cal} = 16620 \, \text{cal}. \] In terms of energy required, melting the ice takes the most energy, as the latent heat of fusion accounts for a significant amount of energy, more than just raising temperatures for the same mass. Finally, you can't simply compute the heat required to melt the ice and add the heat for raising the water temperature because you'd miss the critical index of temperature transition. The energy required for phase change is substantial, so it needs to be calculated separately to provide an accurate picture of thermal energy transitions among solid to liquid states.
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