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Americium -235 has a half-life of 10.3 minutes. The mass of americium- 235 in a sample decays from 1.6 mg to 0.1 mg. How long will this take (in minutes)?

Ask by Wheeler Craig. in the United States
Mar 13,2025

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It takes 41.2 minutes for the americium-235 mass to decay from 1.6 mg to 0.1 mg.

Solución

We start with the exponential decay formula \[ N(t)=N_0\left(\frac{1}{2}\right)^{\frac{t}{T_{1/2}}}, \] where: - \( N(t) \) is the mass at time \( t \), - \( N_0 \) is the initial mass, - \( T_{1/2} \) is the half-life. Given: - \( N_0 = 1.6 \) mg, - \( N(t) = 0.1 \) mg, - \( T_{1/2} = 10.3 \) minutes. Substitute these values into the equation: \[ 0.1 = 1.6\left(\frac{1}{2}\right)^{\frac{t}{10.3}}. \] Divide both sides by 1.6: \[ \left(\frac{1}{2}\right)^{\frac{t}{10.3}} = \frac{0.1}{1.6} = 0.0625. \] Recognize that \[ 0.0625 = \frac{1}{16} = \left(\frac{1}{2}\right)^4. \] Thus, we have: \[ \left(\frac{1}{2}\right)^{\frac{t}{10.3}} = \left(\frac{1}{2}\right)^4. \] Since the bases are the same, the exponents must be equal: \[ \frac{t}{10.3} = 4. \] Now, solve for \( t \): \[ t = 4 \times 10.3 = 41.2 \text{ minutes}. \] Therefore, the mass will decay from 1.6 mg to 0.1 mg in \( 41.2 \) minutes.

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To calculate the time it takes for americium-235 to decay from 1.6 mg to 0.1 mg, we can use the half-life formula. First, we determine how many half-lives it takes to go from 1.6 mg to 0.1 mg: 1.6 mg -> 0.8 mg (1 half-life, 10.3 minutes) 0.8 mg -> 0.4 mg (2 half-lives, 20.6 minutes) 0.4 mg -> 0.2 mg (3 half-lives, 30.9 minutes) 0.2 mg -> 0.1 mg (4 half-lives, 41.2 minutes) It takes four half-lives to reach 0.1 mg. Therefore, 4 x 10.3 minutes = 41.2 minutes. In total, it will take approximately 41.2 minutes for the sample to decay from 1.6 mg to 0.1 mg.

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Química Singapore Mar 20, 2025

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(b) Suggest the structural formula of the final organic product formed when reacted with ethanal, \( \mathrm{CH}_{3} \mathrm{CHO} \), in a similar two-step process. MgBr is [1] (c) The Grignard reagent, \( \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{MgBr} \), can be readily converted into a carboxylic acid by using carbon dioxide. Suggest a two-step reaction sequence for this conversion, giving structural formulae for the compounds involved. \[ \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{MgBr} \cdot \mathrm{CO}_{2} \xrightarrow{\text { step } 1} \square \xrightarrow{\text { stop II }} \square \square \mathrm{Mg}(\mathrm{OH}) \mathrm{Br} \] N10/1/4 12 In 1834 the French chemist Eugene Peligot published his investigations into the action of heat on the Group II salts of carboxylic acids. He discovered that the salts decomposed to give the metal carbonate and a carbonyl compound. This calcium ethanoate produces propanone. \[ \left(\mathrm{CH}_{3} \mathrm{CO}_{2}\right)_{2} \mathrm{Ca} \longrightarrow \mathrm{CaCO}_{3}+\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CO} \] When this reaction is carried out by heating a \( 1: 1 \) molar mixture of calcium ethanoate and calcium methanoate, \( \left(\mathrm{HCO}_{2}\right)_{2} \mathrm{Ca} \), a mixture of three carbonyl compounds is formed, all having \( \mathrm{M}<60 \). (i) Suggest the structures of the three carbonyl compounds, and the ratio in which they might be produced. (ii) Suggest two chemical tests that could be used to distinguish the three carbonyl compounds from each other. You should state what you would observe for each compound in each test. [5] N07/II/
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